Spectrophotometric determination of molybdenum(VI) by solvent extraction of molybdenum (VI)-indoferron chelate
نویسندگان
چکیده
منابع مشابه
Solvent Extraction and Spectrophotometric Determination of Magnesium by Paratoly l-2-Thenohydroxamic Acid and Quinalizarin
Magnesium is extracted with a chloroform solution of N-p-tolyl-2- thenohydroxamic acid (PTTHA) from aqueous solution of pH 9.5 .Mg-PTTHA complex is colourless and the colour is developed by adding quinalizarin into the extract. lmax and e of the complex are 590nm and 2.8´103 Lmol -1cm-1respectively.Most common ions do not interfere in the determination of magnesi...
متن کاملSpectrophotometric determination of molybdenum using surfactant-mediated liquid–liquid extraction
A new spectrophotometric method has been developed for determination of molybdenum using surfactantmediated liquid–liquid extraction. Molybdenum(V) obtained by ascorbic acid reduction in 2.5 M H2SO4 reacted spontaneously with thiocyanate and cetyl trimethyl ammonium bromide (CTAB), forming an intense orange yellow complex that was extracted quantitatively into 1,2-dichloroethane and absorbed at...
متن کاملSOLVENT EXTRACTION AND SPECTROPHOTOMETRIC DETERMINATION OF Mo(VI) BY USING ACETOPHENONE 2’,4’-DIHYDROXY SEMICARBAZONE AS AN ANALYTICAL REAGENT
Acetophenone 2’,4’-dihydroxy semicarbazone (A24DHS) as a photometric reagent for the extractive spectrophotometric determination of Molybdenum (VI) is presented in this paper. The reagent A24DHS gave instantaneous and stable yellow colour with Molybdenum (VI) in the pH range 1.6 to 2.4. The system obeys Beer’s law in the concentration range of 1.0 μg/mL to 8.0 μg/mL at 370 nm. The Limit of Dete...
متن کاملSpectrophotometric Determination of Trace amounts of Molybdenum(VI) Using 4-Hydroxybenzaldehydethiosemicarbazone
The reagent 4-hydroxybenzaldehyde thiosemicarbazone (4-HBTS) has been used for the determination of Mo(VI) by spectrophotometric method. The reagent 4-HBTS gives green colour with Mo(VI) solution of weak acidic medium and the maximum absorbance was observed at 365nm, in acidic buffer p H 6.0. The molar absorptivity and Sandell’s sensitivity of Mo(VI)4-HBTS complex are 1.25 x 10 L mol cm and 0.0...
متن کاملSimultaneolls spectrophotometric determination of molybdenum ( VI ) and titanium ( IV ) using 2 , 4 - dihydroxybenzaldehyde isonicotinoyl hydrazone
Determination of molybdenum(VI) by direct spectrophotometry and simultaneous determination of molybdenum(VI) and titanium(IV) are reported. Molybdenum(VI) gives a golden yellow colour with 2,4dihydroxybenzaldehyde isonicotinoyl hydrazone with a 1:2 metal-reagent stoichiometry at pH 1.5. The complex shows an absorption maximum at 445 nm with molar absorptivity and Sandell's sensitivity of 1.02x1...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: BUNSEKI KAGAKU
سال: 1972
ISSN: 0525-1931
DOI: 10.2116/bunsekikagaku.21.12_1650